MnCaTa2O7—a magnetically ordered polar phase prepared via cation exchange

Reaction between the pseudo-Ruddlesden-Popper phase Li2CaTa2O7 and MnCl2 at 375 °C yields MnCaTa2O7, a paramagnetic polar phase (space group P21nm), which adopts an a–b–c+/b–a–c+ distorted, layered perovskite structure. Magnetization and neutron diffraction data show that MnCaTa2O7 adopts an antifer...

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Bibliografske podrobnosti
Main Authors: Mallick, S, Orlandi, F, Manuel, P, Zhang, W, Halasyamani, PS, Hayward, MA
Format: Journal article
Jezik:English
Izdano: American Chemical Society 2023