Catalytic enantioselective desymmetrisation as a tool for the synthesis of hodgkinsine and hodgkinsine B.

Two palladium-catalysed amination protocols are deployed in the desymmetrisation of the complex dimeric alkaloid meso-chimonanthine. The power of these transformations is showcased in an efficient formal and total synthesis of the natural products hodgkinsine and hodgkinsine B, respectively.

מידע ביבליוגרפי
Main Authors: Snell, R, Durbin, M, Woodward, R, Willis, M
פורמט: Journal article
שפה:English
יצא לאור: 2012
נושאים: