Catalytic enantioselective desymmetrisation as a tool for the synthesis of hodgkinsine and hodgkinsine B.

Two palladium-catalysed amination protocols are deployed in the desymmetrisation of the complex dimeric alkaloid meso-chimonanthine. The power of these transformations is showcased in an efficient formal and total synthesis of the natural products hodgkinsine and hodgkinsine B, respectively.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Snell, R, Durbin, M, Woodward, R, Willis, M
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2012
Нөхцлүүд: