Measurement of the diffusion coefficients of [Ru(NH3)(6)](3+) and [Ru(NH3)(6)](2+) in aqueous solution using microelectrode double potential step chronoamperometry

Microelectrode double potential step chronoamperometry is reported which allows the measurement of the diffusion coefficients of [Ru(NH3) 6]3+ and [Ru(NH3)6]2+ in aqueous solutions containing various concentrations of the supporting electrolyte, KCl, KNO3 or K2SO4. In the case of K2SO4, ion-pairing...

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Détails bibliographiques
Auteurs principaux: Wang, Y, Limon-Petersen, J, Compton, R
Format: Journal article
Langue:English
Publié: 2011