Halide abstraction as a route to cationic transition-metal complexes containing two-coordinate gallium and indium ligand systems

Halide abstraction chemistry offers a viable synthetic route to the cationic two-coordinate complexes [{Cp*Fe(CO)2} 2(μ-E)]+ (7, E = Ga; 8, E = In) featuring linear bridging gallium or indium atoms. Structural, spectroscopic, and computational studies undertaken on 7 are consistent with appreciable...

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Bibliographic Details
Main Authors: Bunn, N, Aldridge, S, Kays, D, Coombs, N, Rossin, A, Willock, D, Day, J, Jones, C, Ooi, L
Format: Journal article
Language:English
Published: 2005