Competing C-F activation pathways: Phosphine participation vs. oxidative addition

Geahča maid

• Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition.
  Dahkki: Nova, A, et al.
  Almmustuhtton: (2008)
• Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation
  Dahkki: Braun, T, et al.
  Almmustuhtton: (2001)
• C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales.
  Dahkki: Clot, E, et al.
  Almmustuhtton: (2011)
• Selective Activation of the ortho C-F Bond in Pentafluoropyridine by Zerovalent Nickel: Reaction via a Metallophosphorane Intermediate Stabilized by Neighboring Group Assistance from the Pyridyl Nitrogen
  Dahkki: Nova, A, et al.
  Almmustuhtton: (2010)
• A comparison of C-F and C-H bond activation by zerovalent ni and pt: a density functional study.
  Dahkki: Reinhold, M, et al.
  Almmustuhtton: (2004)