PHOTOLABILISATION OF PHOSPHINE-LIGANDS BOUND TO IRON - PHOTOFRAGMENTATION VOLTAMMETRY ANALYSIS

Photofragmentation volammetry is used to demonstrate directly the primary loss of P(Ar)3 from [(η5-C5H 5)Fe(CO)(PAr3)=C(NHMe)Me] + BF4- (Ar = phenyl 1 and p-toly 2) on irradiation with visible light. In contrast, no loss of carbon monoxide is observed.

Bibliographic Details
Main Authors: Davies, S, Metzler, M, Watkins, W, Compton, R, Booth, J, Eklund, J
Format: Journal article
Language:English
Published: 1993