A NEW ALLOSTERIC BIS CROWN ETHER LIGAND CONTAINING A 2,2'-BIPYRIDYL FRAGMENT
The synthesis of a new allosteric bis crown ether ligand incorporating a 2,2′-bipyridyl function and two benzo-15-crown-5 subunits is described. Chelation of Ru(II) at the bipyridyl nitrogens forces the bipyridyl function towards coplanarity, restricting the conformational freedom of the two benzo-1...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1988
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