Ti=NR vs Ti-R ' Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective
A study of the reactions of the titanium imido methyl cation [Ti(N tBu)(Me3[9]aneN3)X]+ (5+, X = Me) and key analogues (6+, X = CH2SiMe3; 7+, X = Cl) with a range of unsaturated substrates provides a comprehensive evaluation of reaction site selectivity in transition-metal cations which contain both...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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