B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes.
(Figure Presented) A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine-borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine-borane activation modes within the same molecule. © 2010 Wiley-VCH Verlag GmbH and Co. KG...
Main Authors: | , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2010
|