B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes.

(Figure Presented) A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine-borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine-borane activation modes within the same molecule. © 2010 Wiley-VCH Verlag GmbH and Co. KG...

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Bibliographic Details
Main Authors: Chaplin, AB, Weller, A
Format: Journal article
Language:English
Published: 2010