Tethered aminohydroxylation: dramatic improvements to the process.

[reaction: see text] Changing the identity of the N leaving group on a hydroxylamine-based reoxidant gives a dramatic improvement to the tethered aminohydroxylation reaction. Using OCOC6F5 as a leaving group means that only 1 mol % of osmium is required and yields as high as 98% can be obtained. Acy...

Olles dieđut

Bibliográfalaš dieđut
Váldodahkkit: Donohoe, T, Bataille, C, Gattrell, W, Kloesges, J, Rossignol, E
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2007