Tethered aminohydroxylation: dramatic improvements to the process.
[reaction: see text] Changing the identity of the N leaving group on a hydroxylamine-based reoxidant gives a dramatic improvement to the tethered aminohydroxylation reaction. Using OCOC6F5 as a leaving group means that only 1 mol % of osmium is required and yields as high as 98% can be obtained. Acy...
المؤلفون الرئيسيون: | Donohoe, T, Bataille, C, Gattrell, W, Kloesges, J, Rossignol, E |
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التنسيق: | Journal article |
اللغة: | English |
منشور في: |
2007
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مواد مشابهة
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Tethered Aminohydroxylation
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