Tethered aminohydroxylation: dramatic improvements to the process.

Tethered aminohydroxylation: dramatic improvements to the process.

[reaction: see text] Changing the identity of the N leaving group on a hydroxylamine-based reoxidant gives a dramatic improvement to the tethered aminohydroxylation reaction. Using OCOC6F5 as a leaving group means that only 1 mol % of osmium is required and yields as high as 98% can be obtained. Acy...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों:	Donohoe, T, Bataille, C, Gattrell, W, Kloesges, J, Rossignol, E
स्वरूप:	Journal article
भाषा:	English
प्रकाशित:	2007

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