A conjugated thiophene-based rotaxane: synthesis, spectroscopy, and modeling.
A dithiophene rotaxane 1 subsetbeta-CD and its shape-persistent corresponding dumbbell 1 were synthesized and fully characterized. 2D NOESY experiments, supported by molecular dynamics calculations, revealed a very mobile macrocycle (beta-CD). Steady-state and time-resolved photoluminescence experim...
Main Authors: | Zalewski, L, Wykes, M, Brovelli, S, Bonini, M, Breiner, T, Kastler, M, Dötz, F, Beljonne, D, Anderson, H, Cacialli, F, Samorì, P |
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格式: | Journal article |
語言: | English |
出版: |
2010
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