Catalyst-dependent chemoselective formal insertion of diazo compounds into C-C or C-H bonds of 1,3-dicarbonyl compounds
A catalyst‐dependent chemoselective one‐carbon insertion of diazo compounds into the C−C or C−H bonds of 1,3‐dicarbonyl species is reported. In the presence of silver(I) triflate, diazo insertion into the C(=O)−C bond of the 1,3‐dicarbonyl substrate leads to a 1,4‐dicarbonyl product containing an al...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Published: |
Wiley
2018
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