Sr2FeIrO4: square-planar Ir(II) in an extended oxide
Topochemical reduction of the double-perovskite oxide Sr2FeIrO6 under dilute hydrogen leads to the formation of Sr2FeIrO4. This phase consists of ordered infinite sheets of apex-linked Fe2+O4 and Ir2+O4 squares stacked with Sr2+ cations and is the first report of Ir2+ in an extended oxide phase. Pla...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2018
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