Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(eta(2)-BH(3))Ph(2)PCH(2)PPh(2)}][PF(6)] (COD=1,5-cyclooctadiene)
The rational and high-yield synthesis of [(COD)Rh{(η2-BH3)Ph2PCH2PPh 2}][PF6] (1), which bears a chelating monoborane phosphine, is reported; the solid-state structure shows that the borane coordinates to the metal via two 2e-3c B-H-Rh bonds, which in solution at room temperature are fluxional betwe...
| Hauptverfasser: | , , , , , , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
2001
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