Synthesis and reactivity of the imidotungsten methyl cation [W(N2Npy)(NPh)Me]+: CO2 adds to the W=NPh bond and does not insert into the W-Me bond.

Synthesis and reactivity of the imidotungsten methyl cation [W(N2Npy)(NPh)Me]+: CO2 adds to the W=NPh bond and does not insert into the W-Me bond.

The imidotungsten dimethyl compound [W(N2Npy)(NPh)Me2] 2 reacts with BArF3 to form the cationic complex [W(N2Npy)(NPh)Me]+ 3+ [anion = [MeBArF3]-; ArF = C6F5; N2Npy = MeC(2C5H4N)(CH2NSiMe3)2] which undergoes methyl group exchange with added 2, [Cp2ZrMe2] or ZnMe2; treatment of cation 3+ with CO2 or...

Deskribapen osoa

Xehetasun bibliografikoak
Egile Nagusiak:	Ward, B, Clot, E, Dubberley, SR, Gade, L, Mountford, P
Formatua:	Journal article
Hizkuntza:	English
Argitaratua:	2002

Antzeko izenburuak

Synthesis, reactivity, and computational studies of the cationic tungsten methyl complex [W(NPh)(N2Npy)Me](+) and related compounds (N2Npy = MeC(2-C5H4N)(CH2NSiMe3)(2))
nork: Ward, B, et al.
Argitaratua: (2004)

INTERCONVERSION OF OXO AND IMIDO LIGANDS AT A DIMOLYBDENUM CENTER - MOLECULAR AND ELECTRONIC-STRUCTURE OF [(MO(ETA-C5H4ME)(NPH)(MU-NPH))2]
nork: Green, M, et al.
Argitaratua: (1990)

THE INTERCONVERSION OF OXO AND IMIDO LIGANDS AT A DIMOLYBDENUM CENTER - X-RAY CRYSTAL-STRUCTURE OF [MO(ETA-C5H4ME)(NPH)(MU-NPH)]2
nork: Green, M, et al.
Argitaratua: (1990)

New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand.
nork: Selby, J, et al.
Argitaratua: (2007)

THE INTERCONVERSION OF OXO AND IMIDO LIGANDS AT A DIMOLYBDENUM CENTER - X-RAY CRYSTAL-STRUCTURE OF [(MEC5H4)MO(NPH)(MU-NPH)]2
nork: Green, M, et al.
Argitaratua: (1991)

iNPH—the mystery resolving
nork: Ville Leinonen, et al.
Argitaratua: (2021-02-01)

Does NPH equal ischemia?
nork: Messier Arthur, et al.
Argitaratua: (2007-12-01)

Probable NPH in patients with clinical AD: further support for the AD-NPH syndrome and CSF circulatory failure
nork: Saul T, et al.
Argitaratua: (2004-12-01)

Update on the Cognitive Presentations of iNPH for Clinicians
nork: Tobias Langheinrich, et al.
Argitaratua: (2022-07-01)

The Clinical Utility of the MOCA in iNPH Assessment
nork: Eric Wesner, et al.
Argitaratua: (2022-05-01)

Synthesis and crystallographic characterization of diphenylamide rare-earth metal complexes Ln(NPh2)3(THF)2 and [(Ph2N)2Ln(μ-NPh2)]2
nork: Chad T. Palumbo, et al.
Argitaratua: (2020-09-01)

Rational Design and Modification of NphB for Cannabinoids Biosynthesis
nork: Wenhao Xia, et al.
Argitaratua: (2024-09-01)

Determining the optimum time for assessing NPH patients following CSF drainage – QI study& the development of a patient satisfaction questionnaire – the Newcastle NPH questionnaire
nork: M. Eltayeb, et al.
Argitaratua: (2021-01-01)

L2MX (L2 = PhNC(Me)CHC(Me)NPh ; X=Cl, I ; Μ = Ge, Sn, Pb): NEW THREE COORDINATE DIVALENT GROUP 14 ELEMENT COMPOUNDS
nork: Saur, Isabelle, et al.
Argitaratua: (2002-02-01)

Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations
nork: Bolton, P, et al.
Argitaratua: (2006)

Cerebrospinal Fluid Biomarkers in iNPH: A Narrative Review
nork: Efstratios-Stylianos Pyrgelis, et al.
Argitaratua: (2022-11-01)

Well-defined imidotitanium alkyl cations: agostic interactions, migratory insertion vs.[2+2] cycloaddition, and the first structurally authenticated AlMe(3) adduct of any transition metal alkyl cation.
nork: Bolton, P, et al.
Argitaratua: (2005)

AlMe3 and ZnMe2 adducts of a titanium imido methyl cation: a combined crystallographic, spectroscopic, and DFT study.
nork: Bolton, P, et al.
Argitaratua: (2006)

MRI imaging characteristics of brainstem and midbrain aqueduct in patients with iNPH
nork: Kui Xiao, et al.
Argitaratua: (2025-01-01)

Ventriculoperitoneal shunt patients and glaucoma: a cohort analysis of the NPH registry
nork: Benjam Kemiläinen, et al.
Argitaratua: (2024-07-01)

Ten Steps for NPH Management: Advancements in Diagnosis and Treatment of Adult Hydrocephalus
nork: Alex Roman, et al.
Argitaratua: (2023-09-01)

Functional modeling of the craniospinal system for in-vitro parameter studies on the pathogenesis of NPH
nork: Benninghaus Anne, et al.
Argitaratua: (2017-09-01)

Endoscopic third ventriculostomy (ETV) for idiopathic normal pressure hydrocephalus (iNPH)
nork: Tudor, Katarina Ivana, et al.
Argitaratua: (2016)

Manajemen Perioperatif Gejala Ekstrapiramidal (EPS) pada Hidrocephalus Tekanan Normal (NPH)
nork: Ni Putu Dharmi Lestari, et al.
Argitaratua: (2020-10-01)

Long term prognostic factors in NPH patients after ventriculo-peritoneal shunt
nork: S. Colonna, et al.
Argitaratua: (2022-01-01)

TRPV4 mRNA is elevated in the caudate nucleus with NPH but not in Alzheimer’s disease
nork: Hunter White, et al.
Argitaratua: (2022-11-01)

A new diamido-amine ligand based on three-carbon atom "arms": synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH2CH2CH2NSiMe3)2.
nork: Lowes, T, et al.
Argitaratua: (2005)

Effects of combined treatment with rosiglitazone and NPH insulin on carbohydrate metabolism in patients with type 2 diabetes mellitus
nork: O A Kandalintseva, et al.
Argitaratua: (2008-12-01)

REACTION OF [(ETA-5-C5H4R)CL2W=WCL2(ETA-5-C5H4R)] (R = ME, PR1) WITH ALKYNES - X-RAY CRYSTAL-STRUCTURES OF [(ETA-5-C5H4ME)2W2CL4(MU-C4ME4)] AND [(ETA-5-C5H4ME)2W2CL2(O)(MU-C4ME4)]
nork: Green, M, et al.
Argitaratua: (1990)

Computational Approach to Elucidating Insulin–Protamine Binding Interactions and Dynamics in Insulin NPH Formulations
nork: Ketan Kumar Rohilla, et al.
Argitaratua: (2024-01-01)

Clinical Outcomes After Ventriculo-Peritoneal Shunting in Patients With Classic vs. Complex NPH
nork: Eng Tah Goh, et al.
Argitaratua: (2022-07-01)

Normal pressure hydrocephalus (NPH) is a brain disorder that normally occurs in older adults. It deteriorates functional status and quality of life, particularly ambulation, micturation control, and cognitive ability. NPH patients for which there is no id
nork: Jantana Klaycharoen
Argitaratua: (2016-06-01)

Evaluation of immunogenicity, efficacy and safety of GP40041 compared to Humulin® NPH in patients with type 2 diabetes mellitus
nork: A. G. Zalevskaya, et al.
Argitaratua: (2019-08-01)

Comparative study between two recombinant human NPH insulin formulations for the treatment of type 2 diabetes mellitus
nork: Nelson Rassi, et al.

SYNTHESIS OF THE W=W TRIPLY BONDED DIMERS [W2(ETA-C5H4R)2X4] (X = CL, R = ME OR PR(I) - X = BR, R = PR(I)) AND X-RAY CRYSTAL-STRUCTURES OF [W(ETA-C5H4PR(I))CL4] AND [W2(ETA-C5H4PR(I))2CL4]
nork: Green, M, et al.
Argitaratua: (1990)

A clinical and biochemical analysis in the differential diagnosis of idiopathic normal pressure hydrocephalus (iNPH).
nork: Tommaso eSchirinzi, et al.
Argitaratua: (2015-04-01)

All-Cause and Cause-Specific Mortality among Users of Basal Insulins NPH, Detemir, and Glargine.
nork: Arto Y Strandberg, et al.
Argitaratua: (2016-01-01)

Incidental findings of typical iNPH imaging signs in asymptomatic subjects with subclinical cognitive decline
nork: Doortje C. Engel, et al.
Argitaratua: (2021-08-01)

Regulation of plant phototropic growth by NPH3/RPT2-like substrate phosphorylation and 14-3-3 binding
nork: Stuart Sullivan, et al.
Argitaratua: (2021-10-01)

Safety evaluation of the food enzyme 3‐phytase from the genetically modified Aspergillus niger strain NPH
nork: EFSA Panel on Food Contact Materials, Enzymes and Processing Aids (CEP), et al.
Argitaratua: (2024-01-01)