Thermal Generation and Structures of the Unsaturated Doubly Bridged Complex [Mo2Cp2Cl2(mu-SMe)(2)] and Its Quadruply Bridged Isomer [Mo2Cp2(mu-Cl)(2)(mu-SMe)(2)]
The doubly and quadruply bridged isomers [Mo2Cp 2Cl2(μ-SMe)2] (4) and [Mo2Cp 2(μ-Cl)2(μ-SMe)2] (3) have been obtained as side-products when the dicarbonyl precursor [Mo2Cp 2(CO)2(μ-SMe)3]Cl (1) is warmed in toluene solution, the main product being the tris-thiolato-bridged compound [Mo 2Cp2(μ-Cl)(μ-...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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