Kinetics and mechanism of redox-coupled, long-range proton transfer in an iron-sulfur protein. Investigation by fast-scan protein-film voltammetry
Fast-scan protein-film voltammetry has been used to study and deconvolute the kinetics of proton-coupled electron transfer to and from the [3Fe-4S] cluster in Azotobacter vinelandii Ferredoxin I (Au Fd I). This crystallographically defined 7Fe ferredoxin contains a [3Fe-4S] cluster which takes up a...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1998
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