Electrochemical studies of arsenite oxidase: an unusual example of a highly cooperative two-electron molybdenum center.
Arsenite oxidase from Alcaligenes faecalis, an unusual molybdoenzyme that does not exhibit a Mo(V) EPR signal during oxidative-reductive titrations, has been investigated by protein film voltammetry. A film of the enzyme on a pyrolytic graphite edge electrode produces a sharp two-electron signal ass...
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
2004
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