Electrochemical studies of arsenite oxidase: an unusual example of a highly cooperative two-electron molybdenum center.

Arsenite oxidase from Alcaligenes faecalis, an unusual molybdoenzyme that does not exhibit a Mo(V) EPR signal during oxidative-reductive titrations, has been investigated by protein film voltammetry. A film of the enzyme on a pyrolytic graphite edge electrode produces a sharp two-electron signal ass...

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Bibliographic Details
Main Authors: Hoke, K, Cobb, N, Armstrong, F, Hille, R
Format: Journal article
Language:English
Published: 2004