Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases

Protein film electrochemistry (PFE) has been used to study the assembly of the complex 6Fe active site of [FeFe]-hydrogenases (known as the H-cluster) from its precursors-the [4Fe-4S] domain that is already coordinated within the host, and the 2Fe domain that is presented as a synthetic water-solubl...

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Bibliographic Details
Main Authors: Megarity, C, Esselborn, J, Hexter, S, Wittkamp, F, Apfel, U, Happe, T, Armstrong, F
Format: Journal article
Language:English
Published: American Chemical Society 2016