M=N(alpha) cycloaddition and N(alpha)-N(beta) insertion in the reactions of titanium hydrazido compounds with alkynes: a combined experimental and computational study.

A combined experimental and DFT study of the reactions of diamide-amine supported titanium hydrazides with alkynes is presented. Reaction of Ti(N2N(py))(NNPh2)(py) (1, N2N(py) = (2-NC5H4)CMe(CH2NSiMe3)2) with terminal and internal aryl alkynes ArCCR (Ar = Ph or substituted phenyl, R = Me or H) at ro...

Täydet tiedot

Bibliografiset tiedot
Päätekijät: Schofield, A, Nova, A, Selby, J, Manley, C, Schwarz, A, Clot, E, Mountford, P
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: 2010