Conformational effects in sugar ions: spectroscopic investigations in the gas phase and in solution

We present direct investigations of the conformational preferences of sugars with a positively charged substituent at their anomeric centre, C-1, which display in solution, a preference for an equatorial conformation - an apparent reversal of the normal anomeric effect. The investigations focus on t...

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Bibliographic Details
Main Authors: Sagar, R, Rudic, S, Gamblin, D, Scanlan, E, Vaden, T, Odell, B, Claridge, T, Simons, J, Davis, B
Format: Journal article
Language:English
Published: 2012