Conformational effects in sugar ions: spectroscopic investigations in the gas phase and in solution
We present direct investigations of the conformational preferences of sugars with a positively charged substituent at their anomeric centre, C-1, which display in solution, a preference for an equatorial conformation - an apparent reversal of the normal anomeric effect. The investigations focus on t...
Main Authors: | , , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2012
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