BF 4 (py = pyridine): Evidence for spin exchange along strongly distorted F⋯H⋯F - bridges in a one-dimensional polymeric chain

Figure Persented: [Ni(HF 2)(3-Clpy) 4]BF 4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN 4F 2 octahedra that form chains with bridging HF 2- ligands. In spite of significant distortion of the HF 2- bridge, a quasi-1D antiferromagnetic (AFM) behavior...

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Bibliographic Details
Main Authors: Manson, J, Baldwin, A, Scott, B, Bendix, J, Del Sesto, R, Goddard, P, Kohama, Y, Tran, H, Ghannadzadeh, S, Singleton, J, Lancaster, T, Möller, J, Blundell, S, Pratt, F, Zapf, V, Kang, J, Lee, C, Whangbo, M, Baines, C
Format: Journal article
Language:English
Published: 2012