Synthesis and characterization of a novel N-F reagent derived from the ethano-Troger's base: (1)JFN coupling constants as a signature for the N-F bond.

Methylation of 2,8-dimethyl-6H,12H-5,11-ethanodibenzo[b,f][1,5]-diazocine (ethano-Tröger's base) with methyl iodide followed by ion metathesis and fluorination with N-fluoro-2,3,4,5,6-pentachloropyridinium triflate affords a new electrophilic N-F reagent, that is more reactive than Selectfluor....

Szczegółowa specyfikacja

Opis bibliograficzny
Główni autorzy: Pereira, R, Wolstenhulme, J, Sandford, G, Claridge, T, Gouverneur, V, Cvengroš, J
Format: Journal article
Język:English
Wydane: Royal Society of Chemistry 2015