The thermodynamics and kinetics of electron transfer in the cytochrome P450cam enzyme system.
In anaerobic environments the first electron transfer in substrate-free P450cam is known to be thermodynamically unfavourable, but in the presence of dioxygen the reduction potential for the reaction shifts positively to make electron transfer thermodynamically favourable. Nevertheless a slower rate...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1999
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