Gas pressure effects on the rates of catalytic H(2) oxidation by hydrogenases.
During catalysis by hydrogenases, entities no larger than H(2) or H(+) reach and leave a deeply buried active site, by as yet unidentified pathways. Novel experiments, conducted mainly with the membrane-bound [NiFe]-hydrogenase from Ralstonia eutropha, explore why small excess gas pressures (H(2) or...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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