CONTRASTING LIGAND PHOTOLABILISATIONS IN THE ACETYL COMPLEXES [(ETA(5)-C(5)R(5))FE(CO)(PPH(3))COME] (R=H, ME)
While the primary photochemical process for [(η5-C 5H5)Fe(CO)(PPh3)COMe] is exclusive loss of carbon monoxide to generate [(η5-C5H 5)Fe(CO)(PPh3)Me], that for [(η5-C 5Me5)Fe(CO)(PPh3)COMe] is exclusive loss of triphenylphosphine to generate [(η5-C5Me 5)Fe(CO)2Me].
Main Authors: | , |
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Format: | Journal article |
Language: | English |
Published: |
1994
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