Group 4 permethylindenyl complexes for the polymerisation of L-, D- and rac-lactide monomers

A series of well-defined group 4 permethylindenyl complexes have been prepared and fully characterised by NMR spectroscopy and X-ray crystallography. Me2SB(Cp,I*)ZrCl2 ({(η5-C9Me6)Me2Si(η5-C5H4)}ZrCl2; 1), Me2SB(CpMe,I*)ZrCl2 ({(η5-C9Me6)Me2Si(η5-C5H3Me)}ZrCl2; 2), Me2SB(Cp,I*)HfCl2 (3) and Z-Me2SB(...

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Bibliographic Details
Main Authors: Lamb, JV, Buffet, J-C, Matley, JE, Wright, CMR, Turner, ZR, O'Hare, D
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2019