Exploring the mechanism of the hydroboration of alkenes by amine-boranes catalysed by [Rh(xantphos)](+)

The [Rh(xantphos)]+fragment acts as an effective catalyst for the hydroboration of the alkene TBE (tert-butyl ethene) using the amine-borane H3B·NMe3at low (0.5 mol%) catalyst loadings to give the linear product. Investigations into the mechanism using the initial rate method and labelling studies s...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों: Johnson, H, Torry-Harris, R, Ortega, L, Theron, R, McIndoe, J, Weller, A
स्वरूप: Journal article
भाषा:English
प्रकाशित: Royal Society of Chemistry 2014