Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding
Reduction of a permethylpentalene zirconium(iv) chloride complex [η8-Pn*Zr(μ-Cl)3/2]2(μ-Cl)2Li·THFx with KC8 in benzene results in activation of the aromatic solvent to yield an "inverted sandwich" complex, [η8-Pn*Zr]2(μ-η6:η6-C6H6) (1). The reactions in toluene, cumene, o-xylene and m-xyl...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Jezik: | English |
| Izdano: |
Royal Society of Chemistry
2017
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