Single-wall-carbon-nanotube/single-carbon-chain molecular junctions

Single-wall-carbon-nanotube/single-carbon-chain molecular junctions

Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations sup...

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Κύριοι συγγραφείς: Boerrnert, F, Boerrnert, C, Gorantla, S, Liu, X, Bachmatiuk, A, Joswig, J, Wagner, F, Schaeffel, F, Warner, J, Schoenfelder, R, Rellinghaus, B, Gemming, T, Thomas, J, Knupfer, M, Buechner, B, Ruemmeli, M
Μορφή: Journal article
Γλώσσα:English
Έκδοση: 2010
Περιγραφή
Περίληψη:Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations support the observed stability of such molecular junctions. They also show that short carbon chains bound to other carbon structures are cumulenes and stable semiconductors due to Peierls-like distortion. Junctions like this can be regarded as archetypical building blocks for all-carbon molecular electronics. © 2010 The American Physical Society.

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