Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines
The iridium cyclooctadiene complex incorporating a tricyclopentyl phosphine ligand (PCyp₃), Ir(η²:η²-C₈H₁₂) (PCyp₃)Cl, has been prepared. Removal of the chlorine from this complex using Na[BAr₄<sup>f</sup>][Ar<sup>f</sup> = C₆H₃(CF₃)₂] in CH₂Cl₂/arene solvent results in dehyd...
Main Authors: | , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
Elsevier
2010
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Subjects: |