Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines

The iridium cyclooctadiene complex incorporating a tricyclopentyl phosphine ligand (PCyp₃), Ir(η²:η²-C₈H₁₂) (PCyp₃)Cl, has been prepared. Removal of the chlorine from this complex using Na[BAr₄<sup>f</sup>][Ar<sup>f</sup> = C₆H₃(CF₃)₂] in CH₂Cl₂/arene solvent results in dehyd...

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Main Authors: Moret, S, Dallanegra, R, Chaplin, A, Douglas, T, Hiney, R, Weller, A
格式: Journal article
语言:English
出版: Elsevier 2010
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