Metallization of alkali anions in condensed phases

The Herzfeld criterion for an insulator-to-metal transition is recast here to predict the critical concentration (n(cr)) for metallization of a solution having a solute more polarizable than the host solvent. The Clausius-Mossotti relation applied to the pure solvent shows that its polarizability an...

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Bibliographic Details
Main Authors: Pyper, N, Edwards, P
Format: Journal article
Language:English
Published: 2000