A novel layered oxysulfide intergrowth compound Sr4Mn2Cu5O4S5 containing a fragment of the alpha-Cu2S antifluorite structure.
Sr4Mn2Cu5O4S5 contains manganese oxide sheets separated by unusual antifluorite-type Cu3S3 layers in which copper(I) ions are distributed over three- and four-coordinates sites in a similar fashion to in alpha-Cu2-xS and suggestive of high two-dimensional copper ion mobility.
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2003
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