Theory of asymmetric nonadditive binary hard-sphere mixtures.
It is shown that the formal procedure of integrating out the degrees of freedom of the small spheres in a binary hard-sphere mixture works equally well for nonadditive as it does for additive mixtures. For highly asymmetric mixtures (small size ratios) the resulting effective Hamiltonian of the one-...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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