Exchange coupling through diamagnetic [Fe(CO)4]2- bridging ligands in a xenophilic cluster.

Exchange coupling through diamagnetic [Fe(CO)4]2- bridging ligands in a xenophilic cluster.

The electronic structure of so-called 'xenophilic' clusters, which contain both organometallic fragments and Werner-type paramagnetic transition metal centres, presents a challenge to simple theories of bonding. Density functional theory shows clearly that the cluster Mn(2)(thf)(4)(Fe(CO)(...

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Autori principali:	Krämer, T, Lin, Z, McGrady, J
Natura:	Journal article
Lingua:	English
Pubblicazione:	2011

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