Reversible redox cycling of well-defined, ultra-small Cu/Cu2O nanoparticles

Exceptionally small and well-defined copper (Cu) and cuprite (Cu2O) nanoparticles (NPs) are synthesized by the reaction of mesitylcopper(I) with either H2 or air, respectively. In the presence of sub-stoichiometric quantities of ligands, namely stearic or di(octyl)phosphinic acid (0.1-0.2 equivalent...

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Bibliographic Details
Main Authors: Williams, C, Pike, S, White, E, Regoutz, A, Sammy, N, Payne, D, Shaffer, M
Format: Journal article
Published: American Chemical Society 2017