The topotactic reduction of Sr3Fe2O5Cl2-square planar Fe(II) in an extended oxyhalide.
The topotactic reduction of the oxychloride Sr(3)Fe(2)O(5)Cl(2) with LiH results in the formation of Sr(3)Fe(2)O(4)Cl(2). Neutron powder diffraction data show that Sr(3)Fe(2)O(4)Cl(2) adopts a body-centered tetragonal crystal structure (I4/mmm, a = 4.008(1) Å, c = 22.653(1) Å at 388 K) with anion va...
| Main Authors: | , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2010
|