Hydrogen bonding to hexafluoroisopropanol controls the oxidative strength of hypervalent iodine reagents
Hexafluoroisopropan-2-ol (HFIP) has been found to be an unusually beneficial solvent for undertaking hypervalent iodine-initiated [2+2] cycloaddition of styrenes. For the initiator phenyliodine(III) diacetate (PIDA), voltammetric data demonstrate that the enhanced reactivity in HFIP is due to its gr...
| Váldodahkkit: | , , , , |
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| Materiálatiipa: | Journal article |
| Almmustuhtton: |
American Chemical Society
2016
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