Exploring the ultrafast and isomer-dependent photodissociation of iodothiophenes via site-selective ionization

Exploring the ultrafast and isomer-dependent photodissociation of iodothiophenes via site-selective ionization

C–I bond extension and fission following ultraviolet (UV, 262 nm) photoexcitation of 2- and 3-iodothiophene is studied using ultrafast time-resolved extreme ultraviolet (XUV) ionization in conjunction with velocity map ion imaging. The photoexcited molecules and eventual I atom products are probed b...

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Main Authors: Razmus, WO, Allum, F, Harries, J, Kumagai, Y, Nagaya, K, Bhattacharyya, S, Britton, M, Brouard, M, Bucksbaum, PH, Cheung, K, Crane, SW, Fushitani, M, Gabalski, I, Tatsuo, G, Ghrist, A, Heathcote, D, Hikosaka, Y, Hishikawa, A, Hockett, P, Jones, E, Kukk, E, Iwayama, H, Lam, HVS, McManus, JW, Milesevic, D, Mikosch, J, Minemoto, S, Niozu, A, Orr-Ewing, AJ, Owada, S, Rolles, D, Rudenko, A, Townsend, D, Ueda, K, Unwin, J, Vallance, C, Venkatachalam, AS, Wada, S-I, Walmsley, T, Warne, EM, Woodhouse, JL, Burt, M, Ashfold, MNR, Minns, RS, Forbes, R
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2024

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