HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT
The synthesis of the enantiomeric cis-4-(hydroxymethyl)cyclopent-2-ene-1-ols 2 and 3 (R = H) via a highly enantioselective rearrangement of cis-6-oxabicyclo[3.1.0]hexane-3-methanol 4 (R = H) using the dilithium salts of(+)- or (-)-norephedrine is described. © 1994.
| Autori principali: | , , |
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| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
1994
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| _version_ | 1826285539061399552 |
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| author | Hodgson, D Witherington, J Moloney, B |
| author_facet | Hodgson, D Witherington, J Moloney, B |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | The synthesis of the enantiomeric cis-4-(hydroxymethyl)cyclopent-2-ene-1-ols 2 and 3 (R = H) via a highly enantioselective rearrangement of cis-6-oxabicyclo[3.1.0]hexane-3-methanol 4 (R = H) using the dilithium salts of(+)- or (-)-norephedrine is described. © 1994. |
| first_indexed | 2024-03-07T01:30:19Z |
| format | Journal article |
| id | oxford-uuid:936357fc-4fc2-421d-b5dc-5af6eda73a1e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:30:19Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:936357fc-4fc2-421d-b5dc-5af6eda73a1e2022-03-26T23:31:56ZHIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECTJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:936357fc-4fc2-421d-b5dc-5af6eda73a1eEnglishSymplectic Elements at Oxford1994Hodgson, DWitherington, JMoloney, BThe synthesis of the enantiomeric cis-4-(hydroxymethyl)cyclopent-2-ene-1-ols 2 and 3 (R = H) via a highly enantioselective rearrangement of cis-6-oxabicyclo[3.1.0]hexane-3-methanol 4 (R = H) using the dilithium salts of(+)- or (-)-norephedrine is described. © 1994. |
| spellingShingle | Hodgson, D Witherington, J Moloney, B HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title | HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title_full | HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title_fullStr | HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title_full_unstemmed | HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title_short | HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT |
| title_sort | highly enantioselective rearrangement of a meso epoxide to an allyl alcohol for carbocyclic nucleoside synthesis an internal alkoxide effect |
| work_keys_str_mv | AT hodgsond highlyenantioselectiverearrangementofamesoepoxidetoanallylalcoholforcarbocyclicnucleosidesynthesisaninternalalkoxideeffect AT witheringtonj highlyenantioselectiverearrangementofamesoepoxidetoanallylalcoholforcarbocyclicnucleosidesynthesisaninternalalkoxideeffect AT moloneyb highlyenantioselectiverearrangementofamesoepoxidetoanallylalcoholforcarbocyclicnucleosidesynthesisaninternalalkoxideeffect |