Extreme sensitivity of a topochemical reaction to cation substitution: SrVO2H versus SrV1-xTixO1.5H1.5

The anion-ordered oxide-hydride SrVO2H is an antiferromagnetic insulator due to strong correlations between vanadium d electrons. In an attempt to hole-dope SrVO2H into a metallic state, a strategy of first preparing SrV1-xTixO3 phases and then converting them to the corresponding SrV1-xTixO2H phase...

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Bibliographic Details
Main Authors: Amano Patino, M, Zeng, D, Blundell, S, McGrady, J, Hayward, M
Format: Journal article
Language:English
Published: American Chemical Society 2018