Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis

Reactions of three magnesium(i) dimers, [{( Ar Nacnac)Mg-} 2 ] ( Ar Nacnac = [(ArNCMe) 2 CH] − ; Ar = xylyl (Xyl), mesityl (Mes) or 2,6-diethylphenyl (Dep)), with either 1,1-diphenylethylene (DPE), α-methylstyrene (MS), trans-stilbene (TS) or diphenylacetylene (DPA) led to the 1,2-addition of the M...

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Bibliographic Details
Main Authors: Dange, D, Gair, A, Jones, D, Juckel, M, Aldridge, S, Jones, C
Format: Journal article
Published: Royal Society of Chemistry 2019