Ethylene polymerization using zirconocenes supported on pentafluorophenyl-modified solid polymethylaluminoxane

Three permethylindenyl zirconocenes have been supported on a hexane-insoluble form of polymethylaluminoxane modified with 40 wt % pentafluorophenol (sMAO(PFP)). The solid precatalysts were characterized by solid-state nuclear magnetic resonance spectroscopy, and their ethylene polymerization activit...

Full description

Bibliographic Details
Main Authors: Lamb, JV, Buffet, J-C, Turner, ZR, O'Hare, D
Format: Journal article
Language:English
Published: American Chemical Society 2020