Reactions of a Cyclopentadienyl-Amidinate Titanium Benzimidamido Complex
We report the first reactivity study of a transition-metal benzimidamido complex, namely Cp Ti{PhC(NiPr)2}{NC(ArF 5NOtBu} (5, ArF5= C6F5). Reaction with CO2 and tBuNCO gave the cycloaddition products CpTi{PhC(NiPr)2}{OC(O)N(C{ArF5}NO tBu)} and CpTi{PhC(NiPr)2}{OC(N tBu)N(C{ArF5}NOtBu)} (10), respect...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2014
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