The pH-induced swelling and collapse of a polybase brush synthesized by atom transfer radical polymerization

We have used neutron reflectometry to characterize the swelling behaviour of brushes of poly[2-(diethyl amino)ethyl methacrylate], a polybase, as a function of pH. The brushes, synthesized by the "grafting from" method of atom transfer radical polymerization, were observed to approximately...

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Bibliographic Details
Main Authors: Geoghegan, M, Ruiz-Pérez, L, Dang, C, Parnell, A, Martin, S, Howse, JR, Jones, R, Golestanian, R, Topham, P, Crook, C, Ryan, A, Sivia, D, Webster, J, Menelle, A
Format: Journal article
Language:English
Published: 2006