Radical 1,4-aryl transfer in arylcarboxamides leading to phthalimides, biaryls and enantiomerically enriched beta-arylethylamines

5-exo Cyclisation of vinyl-, aryl- and alkyl-radicals onto the aryl group of arylcarboxamides is followed by β-scission of the resulting spirocyclohexadienyl radicals with ejection of a carbamoyl radical. The fate of this radical depends on the substrate but, in the cases studied, either 5-endo cycl...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron: Robertson, J, Palframan, M, Shea, SA, Tchabanenko, K, Unsworth, W, Winters, C
Fformat: Journal article
Iaith:English
Cyhoeddwyd: 2008