Palladium(II)-catalyzed synthesis of sulfinates from boronic acids and DABSO: a redox-neutral, phosphine-free transformation
A redox-neutral palladium(II)-catalyzed conversion of aryl, heteroaryl, and alkenyl boronic acids into sulfinate intermediates, and onwards to sulfones and sulfonamides, has been realized. A simple Pd(OAc)2 catalyst, in combination with the sulfur dioxide surrogate 1,4-diazabicyclo[2.2.2]octane bis(...
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
Wiley
2016
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